New PDF release: Advances in Catalysis and Related Subjects, Volume 4

By W G Frankenberg

ISBN-10: 0080565085

ISBN-13: 9780080565088

ISBN-10: 012007804X

ISBN-13: 9780120078042

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Extra info for Advances in Catalysis and Related Subjects, Volume 4

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Eng. Chem. 43, 545 (1951). 26. Ries, H. , Advances in Catalysis 4, 88 (1952). [This volume] 27. Emmett, P. , and DeWitt, T. , J . Am. Chem. Soc. 66, 1253 (1943). 28. Webb, G. , Petroleum Processing 2, 497 (1947). 29. Roller, P. , Proc. Am. Testing Materials 32, 607 (1932). 30. Wiley, J. , Deloney, J. , and Denton, S. , Proc. Am. Petroleum Znst. 27 [III],23 (1947). 31. Matheson, G. , Proc. Am. Petroleum Znst. 27 [111], 18 (1947). 32. , Advances in Catalysis, 3, 250 (1951). 33. Ritter, H. , and Drake, L.

26, 94 (1934). 11. Frost, A. , J. Phys. Chem. (USSR) 14, 1313 (1940). 12. Mills, G. , Znd. Ens. Chem. 42, 182 (1950). 13. Evans, L. , Oil Gas J. 44, No. 47, 167 (1946). 14. Marisic, M. S. Patents 2,384,9422,384,946 (1945). 15. Porter, R. , Chem. & Met. Eng. 63, 94 (April 1946). 16. Thomas, C. L. S. Patent 2,270,090 (1942). 17. Ryland, L. , and Tamele, M. W. S. Patent 2,469,314 (1949). 18. Thomas, C. , Znd. Eng. Chem. 41, 2564 (1949). 19. Scheumann, W. , and Rescorla, A. , Oil Gas J. 46, No. 28, 231 (1947).

Bray (22) has suggested the alternative scheme: ks + Clz + HOOCl + Hf + C1’ kr HOOCl + H+ + C1’ + ks HzOz (6) and ( 7 ) 0 2 which leads t o the observed Eq. (b), (e), or (f), depending on the relative values of kT[H+][CI-] and kg. Connick explains Eq. (g) in terms of reaction through the hypohalite ion (reaction 5a), as proposed previously for the iodine reaction which shows the same kinetics a t high pH’s. Alternative schemes using Bray’s assumption of the intermediate HOOCl but involving the more probable ion displacement type of reaction and leading to the same kinetics would be: For Eq.

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Advances in Catalysis and Related Subjects, Volume 4 by W G Frankenberg


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